PDF The Role of Active Elements in the Oxidation Behaviour of High Temperature Metals and Alloys

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For effective protection, the surface of the aluminide coating had to be predominantly platinum and aluminium, and the platinum serves to promote the selective oxidation of the aluminium. The results of a study undertaken at Solar Turbines Incorporated to evaluate the relative corrosion resistance of a range of commercially available diffusion and overlay coatings, typical of those used to protect the base metal superalloys from which gas turbine components are made, have been reported 3.

The work indicated that a silicon aluminide and platinum-chromium aluminide afforded the best protection. Recommendations for coating selection to provide optimised corrosion resistance under various conditions are tabulated. Enter your email address to receive our quarterly alerts. Schaeffer,, G. Download this article Download.

Science, , : — Thermal Barrier Coatings. Philadelphia: Woodhead Publishing Limited, 53— Technical and economical aspects of current thermal barrier coating systems for gas turbine engines by thermal spray and EBPVD: a review [J]. Journal of Thermal Spray Technology, , 17 2 : — Oxidation behaviour of sputter-deposited Ni-Cr-Al micro-crystalline coatings [J].

Acta Materialia, , 46 5 : — Morphologic investigation and growth of the alumina scale on magnetron-sputtered CoCrAl NCs with and without yttrium [J]. Corrosion Science, , 45 10 : — Effects of thermal exposure on structures of DD6 single crystal superalloy with thermal barrier coatings [J]. Journal of Aeronautica Materials, , 36 5 : 38—43 in Chinese. The production of multi-component alloy coatings by particle codeposition [J]. Transactions of the IMF, , 63 1 : — Surface Engineering, , 31 3 : — Electrolytic codeposition of Ni-CrAlY composite coatings using different deposition configurations [J].

These problems are especially dangerous because they are difficult to detect before a part or structure fails. Pitting remains among the most common and damaging forms of corrosion in passivated alloys, [ citation needed ] but it can be prevented by control of the alloy's environment. Pitting results when a small hole, or cavity, forms in the metal, usually as a result of de-passivation of a small area. This area becomes anodic, while part of the remaining metal becomes cathodic, producing a localized galvanic reaction.

The deterioration of this small area penetrates the metal and can lead to failure. This form of corrosion is often difficult to detect due to the fact that it is usually relatively small and may be covered and hidden by corrosion-produced compounds. Stainless steel can pose special corrosion challenges, since its passivating behavior relies on the presence of a major alloying component chromium , at least Because of the elevated temperatures of welding and heat treatment, chromium carbides can form in the grain boundaries of stainless alloys.

This chemical reaction robs the material of chromium in the zone near the grain boundary, making those areas much less resistant to corrosion. This creates a galvanic couple with the well-protected alloy nearby, which leads to "weld decay" corrosion of the grain boundaries in the heat affected zones in highly corrosive environments. This process can seriously reduce the mechanical strength of welded joints over time.

A stainless steel is said to be "sensitized" if chromium carbides are formed in the microstructure. A typical microstructure of a normalized type stainless steel shows no signs of sensitization, while a heavily sensitized steel shows the presence of grain boundary precipitates. The dark lines in the sensitized microstructure are networks of chromium carbides formed along the grain boundaries. Special alloys, either with low carbon content or with added carbon " getters " such as titanium and niobium in types and , respectively , can prevent this effect, but the latter require special heat treatment after welding to prevent the similar phenomenon of "knifeline attack".

As its name implies, corrosion is limited to a very narrow zone adjacent to the weld, often only a few micrometers across, making it even less noticeable.

Crevice corrosion is a localized form of corrosion occurring in confined spaces crevices , to which the access of the working fluid from the environment is limited. Formation of a differential aeration cell leads to corrosion inside the crevices. Examples of crevices are gaps and contact areas between parts, under gaskets or seals, inside cracks and seams, spaces filled with deposits and under sludge piles. Crevice corrosion is influenced by the crevice type metal-metal, metal-nonmetal , crevice geometry size, surface finish , and metallurgical and environmental factors.

The susceptibility to crevice corrosion can be evaluated with ASTM standard procedures. A critical crevice corrosion temperature is commonly used to rank a material's resistance to crevice corrosion. High-temperature corrosion is chemical deterioration of a material typically a metal as a result of heating.


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This non-galvanic form of corrosion can occur when a metal is subjected to a hot atmosphere containing oxygen, sulfur, or other compounds capable of oxidizing or assisting the oxidation of the material concerned. For example, materials used in aerospace, power generation and even in car engines have to resist sustained periods at high temperature in which they may be exposed to an atmosphere containing potentially highly corrosive products of combustion.

The products of high-temperature corrosion can potentially be turned to the advantage of the engineer. The formation of oxides on stainless steels, for example, can provide a protective layer preventing further atmospheric attack, allowing for a material to be used for sustained periods at both room and high temperatures in hostile conditions.

Such high-temperature corrosion products, in the form of compacted oxide layer glazes , prevent or reduce wear during high-temperature sliding contact of metallic or metallic and ceramic surfaces. Thermal oxidation is also commonly used as a route towards the obtainment of controlled oxide nanostructures, including nanowires and thin films. Microbial corrosion , or commonly known as microbiologically influenced corrosion MIC , is a corrosion caused or promoted by microorganisms , usually chemoautotrophs.

It can apply to both metallic and non-metallic materials, in the presence or absence of oxygen. Sulfate-reducing bacteria are active in the absence of oxygen anaerobic ; they produce hydrogen sulfide , causing sulfide stress cracking. In the presence of oxygen aerobic , some bacteria may directly oxidize iron to iron oxides and hydroxides, other bacteria oxidize sulfur and produce sulfuric acid causing biogenic sulfide corrosion.

Concentration cells can form in the deposits of corrosion products, leading to localized corrosion. Accelerated low-water corrosion ALWC is a particularly aggressive form of MIC that affects steel piles in seawater near the low water tide mark. It is characterized by an orange sludge, which smells of hydrogen sulfide when treated with acid. Corrosion rates can be very high and design corrosion allowances can soon be exceeded leading to premature failure of the steel pile.

For unprotected piles, sacrificial anodes can be installed locally to the affected areas to inhibit the corrosion or a complete retrofitted sacrificial anode system can be installed. Affected areas can also be treated using cathodic protection, using either sacrificial anodes or applying current to an inert anode to produce a calcareous deposit, which will help shield the metal from further attack.

Metal dusting is a catastrophic form of corrosion that occurs when susceptible materials are exposed to environments with high carbon activities, such as synthesis gas and other high-CO environments. The corrosion manifests itself as a break-up of bulk metal to metal powder. The suspected mechanism is firstly the deposition of a graphite layer on the surface of the metal, usually from carbon monoxide CO in the vapor phase.

This graphite layer is then thought to form metastable M 3 C species where M is the metal , which migrate away from the metal surface. However, in some regimes no M 3 C species is observed indicating a direct transfer of metal atoms into the graphite layer.

The Role of Active Elements in the Oxidation Behaviour of High Temperature Metals and Alloys

Various treatments are used to slow corrosion damage to metallic objects which are exposed to the weather, salt water, acids, or other hostile environments. Some unprotected metallic alloys are extremely vulnerable to corrosion, such as those used in neodymium magnets , which can spall or crumble into powder even in dry, temperature-stable indoor environments unless properly treated to discourage corrosion.

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When surface treatments are used to retard corrosion, great care must be taken to ensure complete coverage, without gaps, cracks, or pinhole defects. Small defects can act as an " Achilles' heel ", allowing corrosion to penetrate the interior and causing extensive damage even while the outer protective layer remains apparently intact for a period of time. Plating , painting , and the application of enamel are the most common anti-corrosion treatments. Aside from cosmetic and manufacturing issues, there may be tradeoffs in mechanical flexibility versus resistance to abrasion and high temperature.

Platings usually fail only in small sections, but if the plating is more noble than the substrate for example, chromium on steel , a galvanic couple will cause any exposed area to corrode much more rapidly than an unplated surface would. For this reason, it is often wise to plate with active metal such as zinc or cadmium.

If the zinc coating is not thick enough the surface soon becomes unsightly with rusting obvious.

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The design life is directly related to the metal coating thickness. Painting either by roller or brush is more desirable for tight spaces; spray would be better for larger coating areas such as steel decks and waterfront applications. Flexible polyurethane coatings, like Durabak-M26 for example, can provide an anti-corrosive seal with a highly durable slip resistant membrane.

Painted coatings are relatively easy to apply and have fast drying times although temperature and humidity may cause dry times to vary. If the environment is controlled especially in recirculating systems , corrosion inhibitors can often be added to it.

high temperature oxidation-resistant: Topics by terimanisfre.cf

These chemicals form an electrically insulating or chemically impermeable coating on exposed metal surfaces, to suppress electrochemical reactions. Such methods make the system less sensitive to scratches or defects in the coating, since extra inhibitors can be made available wherever metal becomes exposed. Now, corrosion inhibitor barrier layer is available which is nanoengineered to help prevent corrosion on metal surfaces. Chemicals that inhibit corrosion include some of the salts in hard water Roman water systems are famous for their mineral deposits , chromates , phosphates , polyaniline , other conducting polymers and a wide range of specially-designed chemicals that resemble surfactants i.

Alloy and their Properties - Chemistry for All - The Fuse School

Aluminium alloys often undergo a surface treatment. Electrochemical conditions in the bath are carefully adjusted so that uniform pores, several nanometers wide, appear in the metal's oxide film. These pores allow the oxide to grow much thicker than passivating conditions would allow. At the end of the treatment, the pores are allowed to seal, forming a harder-than-usual surface layer. If this coating is scratched, normal passivation processes take over to protect the damaged area.

Anodizing is very resilient to weathering and corrosion, so it is commonly used for building facades and other areas where the surface will come into regular contact with the elements. While being resilient, it must be cleaned frequently. If left without cleaning, panel edge staining will naturally occur. Anodization is the process of converting an anode into cathode by bringing a more active anode in contact with it. A new form of protection has been developed by applying certain species of bacterial films to the surface of metals in highly corrosive environments.

This process increases the corrosion resistance substantially. Alternatively, antimicrobial-producing biofilms can be used to inhibit mild steel corrosion from sulfate-reducing bacteria. Controlled permeability formwork CPF is a method of preventing the corrosion of reinforcement by naturally enhancing the durability of the cover during concrete placement. CPF has been used in environments to combat the effects of carbonation , chlorides, frost and abrasion. Cathodic protection CP is a technique to control the corrosion of a metal surface by making that surface the cathode of an electrochemical cell.

Cathodic protection systems are most commonly used to protect steel pipelines and tanks; steel pier piles , ships, and offshore oil platforms. For effective CP, the potential of the steel surface is polarized pushed more negative until the metal surface has a uniform potential. With a uniform potential, the driving force for the corrosion reaction is halted. For galvanic CP systems, the anode material corrodes under the influence of the steel, and eventually it must be replaced.


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The polarization is caused by the current flow from the anode to the cathode, driven by the difference in electrode potential between the anode and the cathode. The most common sacrificial anode materials are aluminum, zinc, magnesium and related alloys.